There's no button but here's a technique that you could try. But, once again, it involves more than one layer

...
Make your first layer and start drawing whatever the hell you wanted in the opacity you need.
If you accidentally lift the pen off the tablet: create a new layer and continue drawing on that.
(If you lift it off more than once, create a new layer for each time.)
After it's completely finished, ctrl-click on the thumbnail of the first layer in the layers window.
Click on the layer above it and press delete.
(If you made more than one, just keep clicking on the layer above and deleteing.)
Merge those layers (ctrl-e).
Sorry if that's not what you were looking for or if it's too long. I made that up on the spot so it's kinda stupid
